Product ID:ZINC CARBON BATTERIES
MSDS Date:09/12/1995
FSC:6135
NIIN:00-553-6170
MSDS Number: CBSZZ

DURACELL,INC. SUB DART & KRAFT

BERKSHIRE INDUSTRIAL PARK
BETHEL, CT 06801
US

Emergency Phone: 203-796-4682/203-796-4575

Info Phone: 203-796-4292

Cage: 2N182

FORD AEROSPACE CORP

49041 SAN JUAN, CA 95161-9041 US

Telephone: 301-590-9781

Cage: 11530

ZINC (SARA 313) (CERCLA)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 29%

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

MANGANESE DIOXIDE (MNO2)

CAS: 1313-13-9

RTECS: OP0350000

Fraction By Weight: 37%

OSHA PEL 5 MG MN/M3 CEILING

ACGIH TLV: 5 MG MN/M3

ZINC CHLORIDE (SARA 313) (CERCLA) (ZNCL2)

CAS: 7646-85-7

RTECS: ZH1400000

Fraction By Weight: 9%

OSHA PEL 1 MG/M3

ACGIH TLV: 1MG/M3/2STEL(FUME)96

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:THESE CHEMICALS/METALS ARE CONTAINED
IN SEALED CAN.POTENTIAL FOR EXPO SHOULD NOT EXIST UNLESS BATTERY
LEAKS, IS EXPO TO HIGH TEMPERATURE, IS ACCIDENTALLY SWALLOWED OR IS
MECHANICALLY,PHYSICIAL,OR ELEC TRICALLY ABUSED. ACUTE/CHORNIC
HEALTH HAZARDS:NONE.
Explanation of Carcinogenicity:PER
MSDS:CARCINOGENICITY:NTP/IARC/OSHA:NO.
Effects of Overexposure:METAL FUME FEVER SYMPTOMS APPEAR FROM 4-12 HRS
AFTER EXPOSURE & INCLUDE FEVER & SHAKING CHILLS WHICH GENERALLY
DISAPPEAR AFTER 24 HRS.
Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT
GENERALLY AGGRAVATE ANY MEDICAL CONDITION.

First Aid:IF ACCIDENTALLY INGESTED SEE PHYSICIAN AT ONCE.

Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:NOT APPLICABLE. IN CASE OF FIRE IN ADJACENT AREA
IT'S PERMISSIBLE TO USE ANY CLASS OF EXT MEDIUM ON BATT/PKG MATLS.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE SELF-CONTAINED
BREATHING APPARATUS WHEN LG NUMBER OF CELLS ARE INVOLVED IN
FIRE.CELLS MAY RELEASE TOXIC ZINC FUMES WHEN EXPO TO FIRE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:AVOID SKIN/EYE CONTACT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID MECH/ELECTRICAL ABUSE.STORE IN
COOL PLACE BUT PREVENT CONDENSATION ON CELL/BATT TERMINALS.ELEVATED
TEMPS CAN RESULT IN SHORTENED BATT LIFE.
Other Precautions:PROPER STACKING OF CARTONS NO MORE THAN 4 LAYERS HIGH
ON PALLET/NOT MORE THAN 3 PELLETS HIGH.DON'T ATTEMPT TO
RECHARGE.INSTALL CELLS IAW EQPMT INSTRUCTION.REPLACE ALL BATT IN
EQPMT @SAME TIME.DON'T MI X BATT SYS(ALKALINE,ZNCARBON) (SUPPL)

Respiratory Protection:SELF-CONTAINED BREATHING APPARATUS WHEN LARGE
NUMBERS OF CELLS ARE INVOLVED IN FIRE.
Ventilation:SUBSEQUENT TO FIRE, PROVIDE AS MUCH VENTILATION AS
POSSIBLE.
Protective Gloves:USE NEOPRENE,RUBB/LATEX-NITRILE FOR LEAK
Eye Protection:SAFETY GLASES WHEN HNDLG LEAKERS.
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PHY/CHEM CHARACT:BOILING PT(C):ZN 907,ZNCL2 732, MNO2 N/A;VAP PRESS:ZN
1@487C,MNO2 N/A; SOLUBILITY IN H2O:ZN/MNO2 0%, NCL2 432G/100CC;
SPEC GRAV:ZN 7.14, MNO2 5.0, NZCL2 2.9; METL PT(C): ZN 420, MNO2
535. OTHER PRECAUT:IN SAME EQPMT.DON'T CARRY BATT LOOSE IN
POCKET/BAG.

HCC:N1
Boiling Pt:B.P. Text:SUPPLEMENT
Melt/Freeze Pt:M.P/F.P Text:SUPPLEMENT
Decomp Temp:Decomp Text:NP
Vapor Pres:SUPPLEMENT
Vapor Density:NA
Spec Gravity:SUPPLEMENT
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:SUPPLEMENTAL
Appearance and Odor:GRAY.
Percent Volatiles by Volume:NP
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:DO NOT HEAT, DESASSEMBLE, OR RECHARGE.
Hazardous Decomposition Products:WHEN HEATED CELLS MAY EMIT HAZARDOUS
FUMES OF ZINC (ZN).

Waste Disposal Methods:INDIVIDUAL CONSUMERS MAY DISPO W/HOUSEHOLD
TRASH.INDUSTRIAL USERS MUST LANDFILL IAW APPROPRIATE FED/STATE/LOC
REGS.DO NOT INCINERATE, SINCE CELLS MAY EXPLO @EXCESSIVE
TEMPS.DON'T DIPSO OF IN FIRE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.